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鐵礦石燒結過程中不同類型準顆粒的燃燒特性

Combustion characteristics of different types of quasi-particles in iron ore sintering process

  • 摘要: 采用豎直管式爐研究了焦炭粒徑、黏附層、黏附比、焦粉比例對不同類型準顆粒質量轉化率和燃料氮轉化率的影響.結果表明, 對于S和S'型準顆粒, 質量轉化率均隨焦炭粒徑的增大而降低; 對于S'型準顆粒, 燃料氮轉化率隨著焦炭粒徑的增大而減小, 而對于存在黏附層的S型準顆粒, 內核焦炭粒徑越大, 燃料氮轉化率越大; 通過對比S和S'型準顆粒的燃燒情況, 發現黏附層的存在有利于提高準顆粒的質量轉化率和燃料氮轉化率; 對于C型準顆粒, 黏附比越大, 質量轉化率和燃料氮轉化率均越小; P型準顆粒的質量轉化率隨著焦粉比例的增加而減小, 燃料氮轉化率在焦粉比例為50%時達到最低值.

     

    Abstract: The iron ore sintering process is the main source of NOx emissions and accounts for about 48% of the total NOx emissions in the iron and steel industry. The generated NOx is mainly from fuel consumption, and it usually exists in the form of quasi-particle in iron ore sintering bed. Therefore, it is important to deeply understand the combustion characteristics and NOx formation mechanism of quasi-particles in iron ore sintering process. Based on this, the effects of coke breeze particle size, presence of an adhering layer of quasi-particles, adhering ratio of quasi-particle, and coke breeze content on the mass conversion rate of different types of quasiparticles and conversion rate of fuel-N to NOx were investigated in a vertical quartz tube reactor in detail. The results show that the mass conversion rate decreases with increasing coke breeze particle size for S'- and S-type quasi-particles; the conversion rate of fuel-N to NOx decreases with increasing coke breeze particle size for S'-type quasi-particle and exhibits the opposite trend for S-type quasi-particle, which is because of the presence of an adhering layer consisting of fine iron ore and limestone. Considering the combustion characteristics of S-and S'-type quasi-particles, the presence of an adhering layer of quasi-particles favors the increase of mass conversion rate and conversion rate of fuel-N to NOx. The mass conversion rate and conversion rate of fuel-N to NOx both decrease with increasing adhering ratio for C-type quasi-particles whose adhering layer consists of fine limestone and coke breeze. For P-type quasi-particles comprising coke breeze, fine limestone, and fine iron ore, the mass conversion rate decreases with increasing coke breeze content. The conversion rate of fuel-N to NOx is not linear and reaches the lowest value when coke breeze content is 50%.

     

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