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高堿度燒結礦礦相結構分布模式及形成機理

Distribution patterns and formation mechanisms of the mineralogical structure of high basicity sinter

  • 摘要: 基于燒結礦的非均性, 發現了礦相結構的三種分布模式, 并對礦相結構的形成機理進行了闡述.首先, 基于燒結礦的手標本鑒定特征把某鋼廠燒結礦劃分成了三類.其次, 對礦相結構的鑒定發現, 第1類、第2類、第3類這三類燒結礦的礦相結構在空間上依次具有"均一狀、同心環狀、互嵌狀"三種分布模式.均一狀分布的礦相結構形成于溫度較高、還原性較強和混料均勻的穩定條件之中, 主要為交織熔蝕-熔蝕結構, 具有良好的冶金性能; 同心環狀分布的礦相結構從外部帶到內部帶依次為交織熔蝕結構、熔蝕結構和赤鐵礦粒狀結構, 多以獨立單元的形式出現, 其所在區域工藝條件的惡化并不會對燒結礦總體的結構和冶金性能造成太大影響; 交織熔蝕結構、赤鐵礦粒狀結構和鐵酸鈣聚集區交叉形成的互嵌狀礦相結構, 多形成于溫度較低、氣流不穩定和混料不均勻的條件之中, 易成片出現而導致燒結礦結構和冶金性能的惡化.最后, 冶金性能分析顯示, 第1、2類燒結礦各項冶金性能指標良好, 具有互嵌狀分布模式的第3類燒結礦由于礦相結構的不均勻, 冶金性能相對較差.結果表明, 這種基于礦相結構分布模式的研究方式, 有利于對礦相結構形成機理的闡述, 更助于對燒結原料、燒結氣氛等工藝條件的調控, 對燒結礦冶金性能的改善具有一定理論價值.

     

    Abstract: Based on their inhomogeneity, three distribution pattern categories of the mineralogical structure of sinters, and their formation mechanisms, were detailed. First, based on the identifiable characteristics of hand specimens, the sinters in a steel plant were divided into three categories (Category 1, Category 2, Category 3). Second, according to the identification characteristics of the microstructure of sinters, three distribution patterns of the mineralogical structure for the three categories of sinters were established, those being uniform, concentric annular, and intercalated. The homogeneous mineral phase structures, which have good metallurgical properties, are mostly interlaced erosion and erosion structure, and the mineral phase structures are formed under stable conditions with higher temperature, stronger reduction, and uniform mixture. The concentric annular mineralogical structures from the outside to the inner belt are interlaced erosion structure, erosion structure, and hematite granular structure, separately. These structures formed under deteriorative process conditions and have no obvious adverse effect on the overall structure and metallurgical properties of sinters. The intercalated mineral phase structure, formed by the interlaced erosion structure, hematite granular structure, and calcium ferrate accumulation area, is mostly formed under conditions of lower temperature, unstable air flow, and inhomogeneous mixture. Getting together may lead to the deterioration of the structure and metallurgical properties of the sinter. Finally, the results of a metallurgical performance analysis show that the metallurgical index of Category 1 and Category 2 are satisfactory, and Category 3, with its intercalated distribution pattern, shows relatively poor metallurgical performance due to the inhomogeneous structure. The above results indicate that the research method based on the distribution pattern of mineral phase structure can be conducive to the discovery of the formation mechanism of the mineralogical structure, and can help to control the sintering raw materials and sintering atmosphere. It has certain theoretical value for improving the metallurgical properties of sinter.

     

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