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LF精煉渣的氣化脫硫及資源化利用

Gasification desulfurization and resource utilization of ladle furnace refining slag

  • 摘要: 針對我國30多家鋼鐵企業LF精煉渣處理現狀及利用模式進行詳細調研發現:LF精煉渣處理方式較為簡單, 利用層次低, 資源浪費嚴重.同時, LF精煉渣具有光學堿度、硫容量和硫分配比高, 熔化溫度和黏度較低的特點, 可以在冶金內循環利用, 但渣中硫的富集成為其在冶金內循環利用中的限制環節.基于此, 開展LF精煉渣氧化除硫試驗及冶金回用分析研究.結果表明:LF精煉渣中的硫可被O2氧化成SO2;在1370℃和1400℃時, 吹氣10 min除硫率可達47%以上, 而吹氣60 min后除硫率基本可達90%以上, 吹空氣除硫效果明顯, 完全滿足LF精煉渣冶金回用時對硫含量的要求.最終提出了一種簡單高效且與現行生產工藝結合較好的LF精煉渣在冶金中再利用的新思路.

     

    Abstract: The present situation and utilization mode of LF refining slag were investigated in detail for more than 30 typical iron and steel enterprises in China.It is found that the treatment method of LF refining slag is relatively simple, the utilization level is low and the waste of resources is serious.Meanwhile, LF refining slag is characterized by high optical basicity, high sulfur capacity, high sulfur distribution ratio, low melting temperature, and low viscosity.So LF refining slag could be recycled in smelting process, but sulfur enrichment is a restriction factor during the cyclic utilization.To solve this problem, the sulfur removal test and metallurgical recycling utilization of LF refining slag were carried out.The results show that sulfur in LF refining slag can be oxidized to SO2by O2, and it has good desulfurization result when blowing air into the slag at 1643 K and 1673 K.Sulfur removal at 10 min by blowing air is over47%, and over 90%at 60 min, and it can meet the sulfur content requirement of LF refining slag used for smelting process.Finally, a simple and efficient method of LF refining slag used for smelting process is proposed, which goes well with current steelmaking process.

     

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