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稀土金屬脫除氧雜質的新技術及驅動機制研究進展

Research progress on novel technology and mechanisms for the removal of oxygen impurities in rare-earth metals

  • 摘要: 介紹了活潑金屬除氣法、等離子體熔煉法和固溶氫原子除氣法等稀土金屬脫除氧雜質的新方法,詳細歸納了將氧雜質含量限制在5×10-5以下的工藝條件.重點介紹新方法中引入活潑金屬、氫等離子體、活性固溶氫原子等各種外部驅動因素的設計思想,提出提純新技術的同時探究了痕量雜質的遷移規律及去除機制,深化對雜質存在形式、行為規律及提純機理的認識.采用FAST-2D與Stefan數值模擬技術、18O2示蹤同位素標記技術、CALPHAD相圖數據庫模擬計算技術對稀土金屬高純化的新工藝提供理論指導與評價,加深對提純驅動機制的理解.

     

    Abstract: Rare-earth metals play a very important role in the development of high-tech industries and the research of functional materials. The demand for high-purity rare-earth metals has rapidly increased because of the development of modern society and the rare-earth industry. However, the purity of commercial rare-earth metal materials is the key factor limiting the rapid development of rare-earth industry. The major impurities in commercial rare-earth metal materials are gas impurities, especially oxygen. The removal of oxygen impurities is extremely challenging because of their strong affinity, which causes the problem of high oxygen concentrations of raw rare-earth metal materials. Therefore, effectively removing oxygen purities is the key to achieve ultra-high purity rare-earth metals. In recent years, several new and innovative strategies to remove oxygen impurities from rare earth metals have been proposed and investigated. To overcome the kinetic and thermodynamic barriers, various driving forces have been creatively introduced into the refining process. This article presented some novel purification methods to remove oxygen impurities, including active metal external getting method, hydrogen plasma arc melting method and hydrogen in-situ refining method. Experimental results show that the oxygen concentrations in rare-earth metals can be reduced effectively by introducing various driving forces. The optimum process conditions of these techniques were introduced in detail, with the final concentrations of oxygen being reduced to below 5×10-5. The design concept and refining mechanism of the driving forces, including active metal, hydrogen plasma and dissolved active hydrogen atoms in rare-earth metal, were discussed systematically in this paper. The refining principle and migration mechanism of oxygen impurities were also discussed by combined experimental and calculated studies. The FAST-2D combined Stefan simulating method, 18O2 isotope tracking method and CALPHAD method were used to study the purification mechanism. The study results provide theoretical basis for the removal of oxygen impurities in rare-earth metals. The methods demonstrated here may provide insight on the future research in rare-earth purification.

     

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