集輸管道CO2/油/水環境中X65鋼的腐蝕特征
Corrosion characteristics of X65 steel in CO2/oil/water environment of gathering pipeline
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摘要: 通過高溫高壓動態反應釜實驗模擬油田集輸管道腐蝕環境,采用腐蝕失重、X射線衍射、掃描電鏡和電化學分析等方法,研究了CO2/油/水環境中X65鋼的腐蝕行為. 結果表明:不同原油含水率條件下,X65鋼CO2腐蝕形態發生改變. 含水率較低(40%~50%)時,原油的浸潤作用使X65鋼表面發生均勻腐蝕,局部由于原油吸附不均勻出現點蝕特征;含水率在70%~80%之間時,原油對鋼表面屏障作用減弱,生成的產物膜厚而疏松、局部脫落引發臺地腐蝕;含水率為90%時,臺地腐蝕破壞區域擴大,腐蝕加重. 原油可以明顯改變腐蝕產物晶體顆粒大小、堆垛方式、產物膜結構以及化學成分. 在原油的緩蝕作用下,X65鋼CO2腐蝕過程的溫度敏感點向低溫段移動,出現在50℃左右,腐蝕速率降低區間變寬,X65鋼耐蝕性增強.Abstract: The corrosion behavior of X65 steel in the CO2/oil/water environment of gathering pipeline was investigated by mass loss, X-ray powder diffraction (XRD), scanning electron microscopy with X-ray microanalysis (SEM-EDS), and electrochemical analysis through dynamic reactor tests. The results indicate that the corrosion rate increases and the corrosion morphology changes with an increase in the water cut. When the water cut of crude oil is within the range 40%-50%, uniform corrosion occurs along with a lower corrosion rate due to the protection of crude oil, but pitting corrosion appears due to the inhomogeneous adsorption of crude oil. When the water cut is between 70%-80%, the barrier effect of crude oil on the steel surface is weakened, the corrosion scales become thick and loose, and the partial loss of corrosion scales cause mesa corrosion. When the water cut is 90%, the damage area of platform corrosion is enlarged. Consequently, the corrosion rate dramatically increases. Crude oil can hinder the corrosion scales from being dissolved in a corrosive medium and change the dimension and accumulation pattern of the crystal grain, thickness and structure of corrosion scales, thus influencing the corrosion rate. Under the corrosion inhibition effect of crude oil, the temperature-sensitive point of X65 steel corrosion moves to a low temperature at -50℃, lower corrosion rate interval is broadened, and the corrosion resistance of X65 steel is enhanced.