高爐爐缸凝鐵層物相分析
Analysis of the phase of the solid iron layer in blast furnace hearth
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摘要: 在高爐爐缸破損調研的基礎上對高爐爐缸耐火材料熱面凝鐵層進行取樣,利用掃描電子顯微鏡、物相分析等分析手段揭示了凝鐵層的物相組成,并運用Thermol-calc熱力學計算軟件結合TCFE8數據庫對鐵水中石墨碳的析出溫度及析出相分數進行了計算,最后揭示了爐缸凝鐵層物相的形成機理.結果表明,高爐爐缸凝鐵層主要由Fe相和石墨碳相交替分布組成,鐵水成分對石墨碳析出溫度影響較大,石墨碳析出溫度遠高于鐵水凝固溫度,鐵水中C、Si元素含量對石墨碳析出相分數影響較大,而石墨碳析出相可增大鐵水黏度11.9%.凝鐵層中石墨碳的析出主要是由于Fe-耐火材料界面溫度低于石墨碳析出溫度,使得鐵水中C不斷向耐火材料熱面遷移,進而形成Fe-C交替的分層結構.Abstract: The solidified iron layer in blast furnace (BF) hearth was estimated based on the blast furnace damage. The phase compositions of the solidified iron layer were studied using scanning electron microscope and energy dispersive spectrometer. The temperature and proportions of graphite precipitation were calculated by using the Thermol-calc software and the TCFE8 database. Finally, the formation of the solidified iron layer was examined. The results suggest that the solidified iron comprises iron and graphite. The temperature of the graphite precipitation is affected by the composition of the hot metal, and it is much higher than the solidification temperature of the hot metal. The proportions of precipitated graphite are affected by the C and Si in the hot metal, whereas the precipitated graphite increases the viscosity of the hot metal by 11.9%. The graphite precipitates at the interface with the Fe-refractory at lower temperature than that of the graphite saturation, which allows the C migration from the hot metal to the refractory interface.