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BOF-LF-CC工藝生產50CrVA彈簧鋼潔凈度研究

Research on the cleanliness of 50CrVA spring steel produced by the BOF-LF-CC process

  • 摘要: 通過對國內某鋼廠BOF-LF-CC工藝生產50CrVA彈簧鋼進行全流程連續取樣,綜合分析了冶煉過程中總氧(T.O.)、N含量變化,非金屬夾雜物的衍變規律,以及鑄坯中大型夾雜物的特征.結果表明,LF精煉前T.O.和N的平均含量分別為106×10-6和13×10-6,鑄坯中分別為15×10-6和39×10-6,LF過程脫氧效果明顯;運輸和澆注過程存在較明顯的二次氧化現象,需要加強大包到中間包的保護澆注;鑄坯中夾雜物主要為CaOAl2O3-MgO和CaOAl2O3-SiO2復合氧化物夾雜,其中Al2O3含量(質量分數)較高,達到60%~70%,未得到低熔點夾雜物,可通過適當提高精煉渣堿度,或喂入適量鈣線促使夾雜物充分轉變為成分更加均勻的低熔點夾雜物;大型夾雜物以CaO和CaOAl2O3-SiO2-(MgO)球狀氧化物為主,還存在一定比例的純Al2O3夾雜物,需要延長鋼包弱攪拌時間使夾雜物充分上浮.

     

    Abstract: The changes of total oxygen(T. O.) and N contents,the evolution of non-metallic inclusions,and the characteristic of macro-inclusions in casting billets of 50 CrVA spring steel produced by the BOF-LF-CC process were studied by continuous sampling at different stages. Results show that the average contents of T. O. and N are 106×10-6 and 13×10-6 at LF-start,respectively,and they become 15×10-6 and 39×10-6 in billets,indicating that the deoxidization effect in the LF refining process is obvious. However,reoxidation phenomenon is obvious in the transportation and casting processes,so it is necessary to strengthen the steel stream protection from ladle to tundish. The CaO-Al2O3-MgO and CaO-Al2O3-SiO2 composite oxide inclusions are the main inclusions in billets,the Al2O3 content in those inclusions is as high as 60%-70%,and no low-melting inclusion is obtained. The low-melting inclusion can be obtained by increasing the slag basicity or feeding a proper content of Ca wire. Large-size inclusions are primarily composed of CaO and CaOAl2O3-SiO2-(MgO) spherical oxides as well as a certain proportion of pure Al2O3 inclusions. It is necessary to extend the soft stirring time in the ladle to make inclusions float fully.

     

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