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TP347H精煉渣二次氧化控制及夾雜物變性處理

Reoxidation control of refining slag and inclusion modification in TP347H stainless steel

  • 摘要: 研究了采用EF+VOD+IC工藝流程生產TP347H不銹鋼時由于精煉渣成分產生的二次氧化及其氧化夾雜物的變性處理過程.試驗中VOD精煉過程中采用Al進行終脫氧,降低精煉渣中FeO、SiO2含量,精煉渣四元堿度控制在1.3以上,保證鋼中全氧質量分數小于0.003%.脫氧后使用喂Ca-Si線及鋼包軟吹的精煉手段,可將硬質Al2O3及MgAl2O4轉變為CaO-Al2O3夾雜,減少硬質MgAl2O4夾雜總量并使夾雜物熔點低于1500℃.此類夾雜在煉鋼溫度下呈液態且更易于聚集與上浮,而在后續軋制、鍛造過程中低熔點夾雜隨基體發生形變,減少鋼材裂紋的產生.

     

    Abstract: The secondary oxidation caused by compositions of refining slag and Ca treatment on oxide inclusion was studied in TP347H stainless steel by EF+VOD+IC process. In industrial trials, the aluminum is used as the final deoxidation during VOD process. The FeO and SiO2 contents in refining are decreased and the quaternary basicity is higher than 1.3. Then the total oxygen content is below 0.003%. With Ca-Si wire feeding and soft blowing the hard Al2O3 and MgAl2O4 inclusions are transformed to CaO-Al2O3 inclusion. The amount of MgAl2O4 inclusion is reduced and the melting point of inclusion is below 1500℃. This kind of inclu-sion is liquid during steelmaking process and it is easy to coalescence and flotation. And in the following rolling and forging process the inclusions have a little deforming ability with the matrix deformed and prevent the ingot crack.

     

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