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光照對Q450NQR1耐候鋼在干濕交替下腐蝕行為的影響

Effect of light on the corrosion behavior of Q450NQR1 weathering steel inthe wet-dry cycle condition

  • 摘要: 采用腐蝕質量損失、掃描電子顯微鏡、X射線衍射儀、線性極化等測試手段,研究無光照、半光照及全光照三種實驗條件對Q450NQR1耐候鋼在干濕交替條件下腐蝕行為的影響規律.結果表明:光照對實驗鋼干濕交替腐蝕過程影響顯著.實驗鋼在腐蝕前期(48 h)腐蝕速率大小依次為半光照、無光照和全光照,腐蝕中后期(72~96 h)腐蝕速率由大到小依次為半光照、全光照和無光照.腐蝕宏觀形貌有明顯差別,無光照時試樣腐蝕產物呈淤泥狀分布整個表面,有光照條件時腐蝕產物則呈顆粒狀分布,但全光照條件時腐蝕產物顆粒更細且孔隙更小.另外,三種條件下腐蝕產物物相組成一致,但含量有所不同.線性極化測試得出96 h極化電阻由大到小依次為無光照、全光照和半光照,這一結果與通過腐蝕失重得出的腐蝕速率結果一致.

     

    Abstract: The effects of no light, half-day light and all-day light on the corrosion behavior of Q450NQR1 weathering steel in the wet-dry cycle condition were examined by corrosion mass loss, scanning electron microscopy, X-ray diffraction and linear polarization tests. The results indicate that light significantly affects the corrosion process in the wet-dry cycles. In the early stage of steel corrosion (before 48h), the corrosion rate from fast to slow is followed by half-day light, no light, and all-day light; but in the later period (72-96 h), the corrosion rate is ordered by half-day light, all-day light, and no light. The corrosion morphologies are obviously different. The corrosion products are silt-shape distribution in no light condition and particulate distribution in light condition, while they are particle-distributed with finer particles and smaller pores in all-day light condition. X-ray diffraction results show that the corrosion products are the same, but the contents are different in the three conditions. By linear polarization tests, the polarization resistance is obtained in the order from fast to slow of no light, half-day light, and all-day light at 96 h, which is well consistent with the order of corrosion mass loss rate.

     

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