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煤粉與半焦的混合燃燒特性及動力學分析

Combustion characteristics and kinetic analysis of pulverized coal and semicoke

  • 摘要: 為探究煤粉添加半焦后混合燃料的燃燒性能,通過熱重分析研究煤、半焦及其混合物的燃燒過程,得到燃燒特性參數.由于不同溫度區間的燃燒反應機理不同,利用分段法對燃燒過程進行動力學分析,對燃燒反應的前、后期分別使用縮核反應模型和縮核內擴散模型進行模擬,從而得到動力學參數.結果顯示,隨著混合燃料中半焦含量增加,其可燃性指數和燃燒特性指數都減少,燃燒前期活化能由76.79kJ·mol-1增加到92.75kj·mol-1,后期活化能由102.62kJ·mol-1增加到107.94kJ·mol-1.說明半焦的添加會降低混合燃料的燃燒性能.對比不同半焦含量的混合燃料的燃燒特性參數和動力學參數,半焦的質量分數應控制在15%以內最適宜.

     

    Abstract: To explore the combustion performance of blended fuels after adding semicoke, the combustion processes of coal, semieoke, and their mixture were studied by thermogravimetric analysis (TGA) and the combustion characteristic parameters were obtained. Due to the different mechanisms in different temperature ranges of combustion reaction, the kinetics of the combustion process was analyzed by the sectioning method, and the shrinking core models of interracial chemical reaction and internal diffusion were used to model the process at the earlier stage and the later stage to obtain the kinetic parameters, respectively. The results show that with increasing semicoke content in blended fuels, the ignition index and the combustion characteristic index decrease, and the combustion activation energy of blended fuels increases from 76.79 kJ·mol-1 to 92.75 kJ·mol-1 at the earlier stage and from 102.62 kJ·mol-1 to 107.94 kJ·mol-1 at the later stage. It is demonstrated that the combustion performance of blended fuel deteriorates with the increasing semicoke content. By comparing the combustion characteristic parameters and kinetic parameters of blended fuels with different semicoke contents, the mass fraction of semicoke should be controlled below 15%.

     

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