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鉻鐵礦球團焙燒固結特性

Oxidation consolidation characteristics of chromite pellets during the roasting process

  • 摘要: 本文系統研究鉻鐵礦球團的焙燒固結特性.結果表明:預熱時間對于預熱球強度影響不大,在預熱時間為10 min時,隨著預熱溫度的提高,預熱球強度和氧化率呈直線型增加,適宜溫度為1050℃,此時預熱球強度可達每個400 N以上;與傳統鐵礦球團相比,鉻鐵礦球團焙燒所需的溫度高,焙燒時間為10 min時,焙燒溫度從1250℃提高到1350℃,球團強度從每個1078 N提高到1973 N.在鉻鐵礦球團預熱和焙燒過程中,鉻尖晶石(Fe,Mg)(Cr,Fe,Al)2O4氧化生成富鎂的(Fe,Mg)(Cr,Fe,Al)2O4和鉻鐵鋁復合氧化物(Cr,Fe,Al)2O3,當溫度高于1000℃時,(Cr,Fe,Al)2O3新相生成,其主要以環狀分布在顆粒外層,顆粒內部為針狀與(Fe,Mg)(Cr,Fe,Al)2O4形成交織結構,降低Cr/Fe比或升高焙燒溫度均有助于(Cr,Fe,Al)2O3向顆粒外層富集和再結晶長大,有利于球團的固結,提高球團強度.

     

    Abstract: The roasting consolidation characteristics of chromite pellets were systematically studied in this paper. The results show that preheating time has little effect on the compressive strength of preheating chromite pellets. Under the appropriate preheating time of 10 min,increasing the preheating temperature can improve the compressive strength and oxidation rate of preheating chromite pellets linearly. The appropriate preheating temperature is 1050℃,at which the compressive strength of preheating chromite pellets can reach more than 400 N. In addition,compared with conventional iron ore pellets,a higher roasting temperature is required for chromite pellets. The compressive strength of chromite pellets increases from 1078 N to 1973 N when the roasting temperature increases from 1250℃ to 1350℃. During the preheating and roasting of chromite pellets,(Fe,Mg)(Cr,Fe,Al)2O4 is oxidized into(Fe,Mg)(Cr,Fe,Al)2O4 and(Cr,Fe,Al)2O3. The new phase(Cr,Fe,Al)2O3 is obviously generated when the temperature surpasses 1000℃.(Cr,Fe,Al)2O3 mainly distributes in the outer layer of the particles in a ring shape,while the acicular(Cr,Fe,Al)2O3 interlaces together with(Fe,Mg)(Cr,Fe,Al)2O4 in the internal part. Decreasing the Cr/Fe ratio in the raw ore concentrate or increasing the roasting temperature can facilitate the aggregation of(Cr,Fe,Al)2O3 around the outer layer of the particles,which in terms assists in the pellet consolidation and then enhances the compressive strength of chromite pellets.

     

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