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SiO2對燒結礦冶金性能及微觀結構的影響

Effects of SiO2 on the metallurgical properties and microstructure of sinter

  • 摘要: 為給高鐵低硅燒結礦的生產提供理論依據,設計燒結礦堿度R為1.8、1.9和2.0,每種堿度下以SiO2含量為變量,產生12組配礦方案進行燒結杯實驗,研究SiO2對燒結礦冶金性能及微觀結構的影響.結果表明:SiO2質量分數從4.8%~5.7%增加時,其冷態強度逐漸增加,最大增幅為8%;燒結礦還原性逐漸降低,降幅區間為從86.80%到81.01%;還原粉化指數RDI+3.15逐漸增大,增幅區間為從75.95%到87.21%;對于軟熔性能,其軟化開始溫度T10在4.8%~5.4%的SiO2含量區間先升高,在5.4%~5.7%之間又降低,而軟化區間有變寬的趨勢.選定一個堿度水平R=2.0,燒結礦SiO2質量分數在4.8%~5.7%范圍變化時,其微觀結構由熔蝕狀向針柱狀發展,結構均勻性逐漸提高,主要礦物組成由赤鐵礦向鐵酸鈣發展,且低溫還原粉化的骸晶狀赤鐵礦逐漸消失.

     

    Abstract: In order to provide a theoretical basis for the production of high iron and low silica sinter,the basicity(R) was set to 1.8,1.9 and 2.0,the SiO2 content was variable for each alkalinity,and then 12 groups of ore blending schemes were generated to proceed with sinter pot tests. After that,the influences of SiO2 on the metallurgical properties and microstructure of sinter were researched. The results show that when the SiO2 content increases from 4.8% to 5.7%,the cold intensity gradually increases,and the greatest growing rate is 8%; the sinter reducibility tends to lower,and the decreasing range is from 86.80% to 81.01%; the reduction degradation index(RDI+3.15) gradually increases,and the growing range is from 75.95% to 87.21%. For softening-melting properties,the apparent initial softening temperature(T10) previously increases in the range from 4.8% to 5.4% and then decreases in the range from 5.4% to 5.7%,and the softening range has a widening trend. Selected a alkalinity level R=2.0,when the SiO2 content changes in the range of 4.8% to 5.7%,the microstructure of sinter develops from an ablation shape to a needle-like and columnar shape,the structural uniformity gradually improves,and the main mineral composition changes from hematite to calcium ferrite. Skeletal crystalline hematite,which leads to a low temperature reduction degradation phenomenon,gradually disappears.

     

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