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低氧特殊鋼中大尺寸DS類夾雜物生成機理

Formation mechanism of oversized DS-type inclusions in low oxygen special steel

  • 摘要: 為了探討低氧特殊鋼中大尺寸DS類夾雜物的生成機理,通過ASPEX PSEM explorer自動掃描電鏡對比分析國內外低氧特殊鋼試樣中夾雜物特征(國內、外試樣各兩個),發現國內試樣中夾雜物平均尺寸大于國外試樣,夾雜物的最大尺寸則數倍于國外試樣:國內試樣中夾雜物的最大尺寸分別為24.9和13.1μm,國外試樣分別為7.6和7.5μm.對比國內外特鋼試樣中大尺寸與小尺寸夾雜物可發現二者成分基本相同,推斷大尺寸DS類夾雜物可能是細小夾雜物碰撞長大而形成.通過分析大尺寸夾雜物的可能來源,在實驗室通過高溫共聚焦激光掃描顯微鏡觀察夾雜物在鋼中固/液相界面處的行為.結果發現,總氧降低至7×10-6時,尺寸5μm以下的微細夾雜物可被固/液相界面所捕捉,并在固/液相界面處發生碰撞、聚集、長大而生成大尺寸(>12μm)DS類夾雜物.

     

    Abstract: To investigate the generation mechanism of oversized DS-type inclusions in low oxygen special steel,a comparative analysis of inclusions was performed on overseas and domestic special steel samples by the automatic secondary electron microscopy ASPEX PSEM explorer.Both the average size and maximum size of inclusions are larger in domestic samples than overseas samples.Particularly,the maximum size of inclusions in domestic samples is several times that in overseas steel samples:24.9 and 13.1 μm in domestic samples and 7.6 and 7.5 μm in overseas samples,respectively.Based on the chemical composition analysis of inclusions in domestic samples,it is found that the oversized inclusions and smaller inclusions have similar compositions.Therefore,the detected DS-type inclusions are endogenous but not exogenous,which can be produced by collisions among inclusion particles.To further study the possible origins of the oversized DS-type inclusions,in-situ observation on the behaviors of inclusions at the solid/liquid interface in low oxygen special steel show that tiny inclusions less than 5 μm can be easily and stably captured by the solid/liquid interface with a total oxygen content of 7×10-6.Moreover,collisions,agglomeration/coalescence and growth of inclusions captured by the solid/liquid interface result in the formation of much larger size DS-type inclusions over >12 μm.

     

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