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硼鐵精礦的碳熱還原動力學

Carbothermic reduction kinetics of boron-bearing iron concentrate

  • 摘要: 為了揭示硼鐵精礦的碳熱還原機理,以高純石墨為還原劑,進行硼鐵精礦含碳球團等溫還原實驗,并采用積分法進行動力學分析.還原溫度分別設定為1000、1050、1100、1150、1200、1250和1300℃,配碳量即C/O摩爾比=1.0.當還原度為0.1<α<0.8時,溫度對活化能和速率控制環節有重要影響:還原溫度≤1100℃時,平均活化能為202.6 k J·mol-1,還原反應的速率控制環節為碳的氣化反應;還原溫度>1100℃時,平均活化能為116.7 k J·mol-1,為碳氣化反應和Fe O還原反應共同控制.當還原度α≥0.8時(還原溫度>1100℃),可能的速率控制環節為碳原子在金屬鐵中的擴散.碳氣化反應是含碳球團還原過程中主要速率控制環節,原因在于硼鐵精礦中硼元素對碳氣化反應具有較強烈的化學抑制作用.

     

    Abstract: In order to deeply understand the carbothermic reduction mechanism of boron-bearing iron concentrate,the isothermal reduction of boron-bearing iron concentrate/carbon composite pellets was performed with high purity graphite as a reductant,and was kinetically analyzed by the integration method. The reduction temperature was set as 1000,1050,1100,1150,1200,1250 and 1300℃,and the C/O molar ratio was 1.0. When the reduction degree ranged from 0.1 to 0.8,the reduction temperature had important effect on the apparent activation energy and rate controlling step. If the reduction temperature was not greater than 1100℃,the average apparent activation energy was 202.6 k J·mol-1,and the rate controlling step was carbon gasification. But if the reduction temperature was higher than 1100℃,the average apparent activation energy was 116.7 k J·mol-1,and the reduction rate was the mixed control of carbon gasification and Fe O reduction reaction. When the reduction degree was not less than 0.8(reduction temperature 〉1100℃),the reduction might be controlled by carbon diffusion in metallic iron. Carbon gasification is the main rate controlling step for the reduction of the composite pellet due to the intense chemical inhibition effect of boron in the boron-bearing iron concentrate on carbon gasification.

     

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