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無取向電工鋼脫碳組織的動力學分析

Kinetic analysis of decarburized microstructure in non-oriented electrical steel

  • 摘要: 無取向電工鋼兩相區脫碳退火獲得柱狀鐵素體晶粒可有效改善材料組織的均勻性.本文從動力學角度分析柱狀晶的生長過程.柱狀晶的形成分為‘形核’和定向生長兩個階段,其中定向生長過程本質上是反應擴散和再結晶長大共同引起的界面遷移,且在動力學上符合拋物線規律,但其生長速率與退火溫度之間并非呈單調的變化關系,而是在900℃時呈極大值.最后結合柱狀晶生長速率的導出公式得到柱狀晶‘晶核’的尺寸約束條件,這對實際生產過程中無取向電工鋼脫碳工藝的設計有一定的指導意義.

     

    Abstract: Decarburization of non-oriented electrical steel in the two-phase region is a known method to acquire a columnar ferrite structure which may effectively ameliorate the microstructure homogeneity of materials. In this paper,the growth process of columnar grains was analyzed from the kinetics point of view. The results show that the columnar structure formation involves two stages:nucleation and directed growth. Directed growth is a sort of interface migration process caused by both reaction-diffusion and recrystallization growth,and fits a parabolic law. The growth rate and the annealing temperature do not show a monotonic functional relationship,but the growth rate reaches a maximal value when the temperature is 900℃. At last,we get the size constraint condition of columnar nuclei on the basis of the derived growth rate formula,which may present some significance for guiding the design of relevant decarburization parameters in industrial production.

     

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