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鹽霧對噴錫和化金印制電路板腐蝕行為的影響

Effect of salt spray environment on the corrosion behavior of PCB-HASL and PCB-ENIG

  • 摘要: 采用交流阻抗譜研究熱風整平無鉛噴錫處理印制電路板(PCB-HASL)和無電鍍鎳金電路板(PCB-ENIG)在鹽霧環境下的電化學腐蝕行為,并結合體式學顯微鏡、掃描電鏡、X射線能譜等手段分析兩種不同表面處理工藝電路板的腐蝕產物形貌、組成和鍍層失效機制.結果表明:鹽霧環境下,PCB-HASL和PCB-ENIG均發生嚴重腐蝕;鍍Sn層開始發生局部腐蝕,隨后幾乎整個表面都發生腐蝕,出現類似均勻腐蝕的現象,鍍金板主要發生微孔腐蝕.在PCB-HASL腐蝕過程中,Cl-的侵蝕作用促進Sn層的腐蝕,后來由于逐漸形成大量的覆蓋在鍍層表面的腐蝕產物,使得腐蝕速率降低;而在PCB-ENIG腐蝕過程中,微孔處形成含Cl-電解質薄液層,Ni與Au構成腐蝕電偶,從而加速Ni的腐蝕,最終使Cu基底裸露,造成電路板失效.

     

    Abstract: The corrosion behavior of hot air solder level printed circuit boards(PCB-HASL) and electroless nickel immersion gold printed circuit boards(PCB-ENIG) in salt spray test was studied by electrochemical impedance spectroscopy. The corrosion product morphology,composition and coating failure mechanism were observed by stereo microscopy,scanning electron microscopy and energy-dispersive X-ray spectroscopy. The results show that PCB-HASL and PCB-ENIG suffer severe corrosion in high salt spray environment. Localized corrosion occurs first in the Sn plating layer,and then almost entire surface corrosion occurs,similar to uniform corrosion. PCB-ENIG mainly generates microporous corrosion. In the PCB-HASL corrosion process,Cl- promotes the corrosion of the Sn layer,then a large amount of corrosion product gradually forms and covers the Sn surface,it makes the corrosion rate reduce.In the PCB-ENIG corrosion process,a thin liquid layer containing Cl- electrolyte forms in micropores,and galvanic coupling between gold and nickel constitutes,which accelerates Ni corrosion. The Cu base directly exposes in the adverse environment after Ni suffers serious corrosion,finally leading to electronic component failure.

     

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