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石膏種類對富水充填材料凝結硬化性能與機理的影響

Impact of gypsum type on the setting and hardening performance and mechanism of water-rich filling materials

  • 摘要: 針對富水充填材料的凝結性能受石膏種類影響的問題,采用X射線衍射、掃描電鏡、紅外光譜等微觀實驗,分析富水充填材料硬化體的組成,探討二水石膏和半水石膏對富水充填材料性能影響的機理.結果表明:以硫鋁酸鹽水泥-石膏-石灰為主的富水充填材料體系中,為保證正常的凝結硬化,石膏應為二水石膏;如以半水石膏為原材料,在7 d齡期時仍不具有強度;二水石膏充足時生成的鈣礬石晶體呈細針狀,二水石膏不足時生成的鈣礬石晶體為六棱短柱狀;富水充填材料的強度主要來源于硫鋁酸鹽水泥-石膏-石灰反應生成的鈣礬石,而不是水泥自身水化的水化硫鋁酸鈣、鋁膠和氫氧化鈣.

     

    Abstract: As for the problem that different gypsum types have different influence on the condensation performance of water-rich filling materials,micro experiments,such as X-ray diffraction,scanning electron microscopy and infrared spectroscopy,were used to analyze the composition of the hardened body and investigate the influence of dihydrate gypsum and hemihydrate gypsum on the setting and hardening characteristics of water-rich filling materials. It is found that in a water-rich filling material system of sulphoaluminate cement-gypsum-lime,the gypsum type should be dihydrate gypsum so as to ensure the normal condensation setting and hardening; if hemihydrate gypsum is used as a raw material,the water-rich filling material has not strength after hydrating for 7 d. When dihydrate gypsum is adequate,the generated ettringite crystals are fine needle-like; but when dihydrate gypsum is inadequate,the generated ettringite crystals are short hexagonal columnar. The strength of the water-rich filling material is mainly derived from ettringite generated by the reaction of sulphoaluminate cement gypsum and lime,rather than the hydration products of cement generated by itself such as hydration calcium sulphoaluminate,alumina gel and calcium hydroxide.

     

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