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高磷礦氫氣還原過程的原位研究

In-situ research on the H2 based reduction process of high-phosphorous iron ore

  • 摘要: 通過原位觀察的方法,研究了H2氣氛、不同溫度下高磷礦還原過程的礦相結構演變規律和溫度對金屬鐵析出形態的影響.高磷礦的鮞狀結構在還原過程中未被破壞掉;隨著溫度的提高,礦相結構的演變加快,溫度較高時Fe發生明顯偏聚,金屬鐵從赤鐵礦相中加快析出.還原溫度對高磷礦中金屬鐵的析出形態影響顯著:在700℃時金屬鐵析出在礦石顆粒表面形成致密鐵層;800℃時析出的金屬鐵形貌復雜化,鐵層致密度下降,出現孔洞,同時有少量的短小鐵晶須;900℃時鐵晶須數量明顯增多,同時伴隨著大量多孔海綿鐵的析出.因此,可以通過調節還原溫度和時間,使得氣基還原過程避免黏結失流,同時高效還原高磷礦.

     

    Abstract: Based on in-situ observation,mineral evolution in high-phosphorous iron ore during the reduction process was investigated in the H2 atmosphere at different temperatures,and the influence of temperature on the morphology of iron was discussed. During the reduction process,ooliths in the iron ore remain. The mineral phases evolve faster with rising temperature,and so does the precipitation of iron from hematite phase. Significant segregation of iron happens at a higher temperature. Temperature has significant impact on the precipitation morphology of metallic iron. At 700℃,the precipitation of metallic iron forms a dense layer on the surface of particles. At 800℃,the precipitation morphology of metallic iron is complex,the density of the iron layer decreases,little holes appear while a small number of short iron whiskers are found. But at 900℃,the number of iron whiskers significantly increases with abundant porous sponge iron. Therefore,by adjusting the temperature and time,the sticking problem during the gas-based reduction process can be avoided,and meanwhile,efficient reduction of high phosphate iron ore is achieved.

     

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