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燒結溫度對高速壓制制備彌散強化銅材料導電率的影響

Influence of sintering temperature on the electrical conductivity of Al2O3/Cu composites compacted by high velocity compaction

  • 摘要: 彌散強化銅材料具有高強度和高導電性的特性,孔洞是影響導電率的重要因素.本文采用高速壓制成形技術,對Al2O3質量分數為0.9%的彌散強化銅粉壓制成形,研究了壓制速度對生坯的影響.當壓制速度為9.4 m·s-1時得到密度為8.46 g·cm-3的生坯.研究了燒結溫度對燒結所得Al2O3彌散強化銅試樣導電率的影響.當生坯密度相同時,燒結溫度越高,所得試樣的導電率也越高.斷口與金相分析表明:燒結溫度為950℃時,燒結不充分,顆粒邊界以及孔洞多而明顯,孔洞形狀不規則;燒結溫度為1080℃時,顆粒邊界消失,孔洞圓化,韌窩出現,燒結坯的電導率為71.3%IACS.

     

    Abstract: Oxide dispersion strengthening(ODS) copper has the characteristics of both high strength and high conductivity. The porosity is an important factor influencing the electrical conductivity. 0.9Al2O3/Cu powder was compacted by a high velocity compaction(HVC) technique. The influence of impact velocity on the green density of Al2O3 dispersion strengthening copper was studied,and the green density of 8.46 g·cm-3 was got at the impact velocity of 9.4 m·s-1. The dependence of the electrical conductivity on sintering temperature was investigated. The results from sintering steps showed that the higher the sintering temperature was,the higher the electrical conductivity was at the same green density level. Fracture surface and SEM observations indicated that the samples were inadequately sintered at the sintering temperature of 950℃,with particle boundaries and some pores being visible obviously. When the sintering temperature rose up to 1080℃,the pores tended to spheroidize,the particle boundaries disappeared,and the dimples appeared on the fracture surface,showing a typical plastic fracture characteristic. The electrical conductivity of the sintered compacts was measured to be 71.3% IACS.

     

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