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基于熱膨脹法與相體積計算模型研究連鑄坯冷卻過程中奧氏體相變行為

Investigation on austenite transformation in continuously cast steel based on dilatometry and the phase fraction model

  • 摘要: 采用熱膨脹儀測試研究了Q450NQR1鋼連鑄坯5℃·min-1及20℃·min-1冷卻速率下的線性熱膨脹(ΔL/L0)和熱膨脹系數隨溫度的變化規律.在此基礎上,建立了一種基于平均原子體積的相體積計算模型,量化研究了奧氏體相變過程中各相體積分數的變化規律,并在將計算結果與顯微組織觀察結果對比分析基礎上,討論了連鑄冷卻速率對鑄坯奧氏體相變過程的影響.結果表明:該計算模型可以較為準確地描述鑄坯的奧氏體相變過程,適用于多相連續析出相變;隨著冷卻速率的增大,鑄坯熱膨脹曲線中對應于鐵素體和珠光體析出的兩個變化峰向低溫區移動,峰值明顯增大;冷卻速率由5℃·min-1上升至20℃·min-1時,鐵素體及珠光體起始析出溫度分別降低約32℃和37℃,最終體積分數分別由0.894和0.106變為0.945和0.055.

     

    Abstract: To understand the knowledge of liner thermal expansion and thermal expansion coefficient of Q450NQR1 casting steel, dilatometry experiments were performed at two different cooling rates of 5℃·min-1 and 20℃·min-1. A mathematical model was developed to quantitatively extract the kinetic information of austenite transformation based on the concept of average atomic volume. The model was verified by microstructure examinations, indicating that the model was appropriate to describe the behavior of austenite transformation and could be applied to multi-phase transformations during steel continuous casting. The influence of cooling rate on the austenite transformation was discussed with the model. it is found that, with increasing cooling rate, two peaks associated to the precipitation of ferrite and pearlite on the thermal expansion coefficient curve shifted towards a lower temperature region with higher values. As the cooling rate increases from 5℃·min-1 to 20℃·min-1, the initial temperatures of ferrite and pearlite precipitation decrease by 32℃ and 37℃, and the final volume fractions of ferrite and pearlite gradually change from 0.894 and 0.106 to 0.945 and 0.055, respectively.

     

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