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印度尼西亞海砂氧化性球團氫氣還原機理

Hydrogen reduction mechanism of Indonesia ironsand oxidized pellets

  • 摘要: 對印度尼西亞海砂礦氧化性球團氫氣還原的規律做了較詳細的研究.實驗采用失重的方法,通過對反應過程的物相變化、熱力學以及動力學方面的分析,探究了海砂球團礦氫氣還原的機理.結果表明:溫度在800℃和850℃,還原反應的最終產物主要是FeTiO3,整個反應限制環節是由兩個不同階段的過程組成,反應開始階段由界面化學反應控制,之后由界面化學反應與內擴散共同控制;在900、950和1000℃三個溫度下,反應產物中有鈦氧化物出現,整個還原反應由三個不同的限制性環節組成,開始由界面化學反應控制,反應中間階段是由界面化學反應和內擴散共同控制,反應后期則是由內擴散控制為主.

     

    Abstract: This article is focused on the reduction law of Indonesia ironsaud oxidized pellets by hydrogen. Reduction experiment was performed with a thermogravimetric analyzer. The hydrogen reduction mechanism of the oxidized pellets was studied by the phase change, thermodynamic and kinetic analyses of the reaction process. It is found that the final products are FeTiO3 at 800℃ and 850℃, and the restrictive step of reduction is composed of two different stages, which are chemical reaction in the early stage of reduction and the mixed-control of chemical reaction and intraparticle diffusion in the subsequent reaction. Titanium oxide appears at 900, 950 and 1000℃, and the restrictive step of reduction is composed of three stages, which are chemical reaction, the mixed-control of chemical reaction and intraparticle diffusion, and intraparticle diffusion.

     

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