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CSP流程鈦微合金化高強鋼的第二相粒子析出行為

Precipitation behavior of Ti-microalloyed high-strength steel by CSP process

  • 摘要: 采用光學顯微鏡、掃描電鏡、透射電鏡、物理化學相分析等方法并結合熱力學計算,分析了CSP工藝生產的鈦微合金化高強鋼的析出物特征及析出規律.研究發現:屈服強度700 MPa級高強鋼中存在大量球形的納米級TiC和Ti(C,N)粒子及少量不規則形狀、100 nm以上的Ti4C2S2粒子,TiN在連軋前完成析出,TiC主要在卷取和空冷時析出.不含鉬鋼和含鉬鋼(0.1% Mo)中MC相的質量分數為0.049%和0.043%,由于鉬的加入,含鉬鋼中Ti的析出量較少,但析出粒子更為細小,并定量得到了不含鉬鋼和含鉬鋼的析出強化效果分別為126 MPa和128 MPa.

     

    Abstract: Optical microscopy, electron microscopy and physic-chemical phase analysis, in combination with thermodynamic calculations, were used to study precipitates and their precipitation regularity in Ti-microalloyed high-strength steel produced by CSP process. It is found that lots of spherical TiC and Ti(C,N) nanoparticles with a few of irregular shaped Ti4C2S2 above 100 nm in size exist in the steel with a yield strength of 700 MPa. TiN is completely precipitated from the steel before tandem rolling, but TiC mainly precipitates during coiling and cooling. The mass fractions of MC phases in the steel without Mo and the steel containing Mo are 0.049% and 0.043%, respectively. Owing to the addition of molybdenum, the amount of Ti precipitates in the steel containing Mo decreases while the precipitate size becomes smaller. The precipitation strengthening effects of the steel without Mo and the steel containing Mo are 126 MPa and 128 MPa, respectively.

     

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