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316L不銹鋼中氮氣合金化行為

Nitrogen alloying behavior of 316 L stainless steel

  • 摘要: 通過FactSage熱力學計算軟件和實驗室實驗研究了在常壓和真空條件下溫度、氮分壓和碳含量對316L不銹鋼中氮溶解度的影響.結果表明:鋼中氮的溶解度隨著溫度的降低而升高,隨著氮分壓的增大而增大,隨著鋼液碳含量的增加而減少,其中氮分壓對鋼液氮溶解度的影響最大.不同吹氮條件下氮溶解度實測值與FactSage熱力學軟件計算值較吻合.生產控氮型316L不銹鋼可以在吹氧脫碳階段實現,生產氮質量分數大于0.10%的中氮型316L不銹鋼,只能在氮分壓大于30kPa的加料階段以及破真空后大氣微調階段實現.

     

    Abstract: The influences of liquid steel temperature,nitrogen partial pressure,and carbon content on the nitrogen solubility in 316 L stainless steel under normal atmosphere and vacuum were studied by the Factsage thermodynamic calculation software and laboratory experiments. Results show that nitrogen solubility increases with decreasing the liquid steel temperature,increasing the nitrogen partial pressure,or decreasing the carbon content. The nitrogen partial pressure is the most important one among the three parameters.The thermodynamic calculation results are in coincidence with the measurement results in different nitrogen blowing processes. Producing 316 LN with the N content of 0.05%- 0.10%(mass fraction) could be conducted during oxygen blowing. Producing 316 LN with the N content of 0.10%- 0.40% should be carried out during charging(the nitrogen partial pressure must be over 30 kPa) and under atmospheric pressure.

     

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