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煤基處理硫酸渣制備含硫鋼原料的實驗研究

Experimental study on the coal-based method to deal with pyrite cinder for preparing sulfur-bearing steel

  • 摘要: 以含有低熔點FeS2的硫酸渣和煙煤為原料,對硫酸渣含碳球團進行還原熔分,考察了堿度、焙燒溫度、焙燒時間和C/O摩爾比對鐵回收率的影響,確定了最佳工藝參數.在堿度R=1.0、焙燒溫度1450℃、焙燒時間20 min以及配煤量C/O=1.2的條件下還原熔分硫酸渣,可以獲得93.1%鐵回收率的珠鐵.對尾渣的X射線衍射分析可知,硫酸渣中鐵氧化物及含鐵硫化物被還原,鐵回收率較高,且熔分時間短造成大量鐵以金屬態滯留于渣中;還原熔分硫酸渣所得珠鐵因其較高硫含量,可用于冶煉硫系易切削鋼.

     

    Abstract: Using pyrite cinder with low melting point and bituminous coal as raw materials,carbonized pyrite cinder pellets were made and introduced to the reduction smelting process. The effects of basicity,roasting temperature,roasting time and C/O molar ratio on the iron recovery rate were investigated to search the optimum experimental parameters. It was found that iron nuggets with the iron recovery of 93.1% were obtained when the basicity was 1.2,the roasting temperature was 1450℃,the roasting time was 20 min and the C/O molar ratio was 1.2. Iron oxides and iron-bearing sulfides in pyrite cinder were reduced,thus a higher iron recovery rate was achieved. From X-ray diffraction analysis on the slag tailings,short smelting time caused high amount of iron in metallic state retained in the slag. Because of high sulfur in iron nuggets from pyrite cinder by reduction and melting separation,the iron nuggets can be used as raw materials to product sulfur-bearing free-cutting steel.

     

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