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金屬鋰還原罐內化學反應與傳熱耦合特性

Coupled properties of heat transfer and chemical reactions in lithium production retorts

  • 摘要: 為了分析真空熱還原制取金屬鋰的還原效率和還原率,綜合考慮罐內球團傳熱和化學反應,建立了傳熱與反應動力學耦合模型.利用該模型對單球團和還原罐內球團還原過程進行數值模擬,得到了球團溫度及還原率的時間分布,并分析了罐外換熱系數對球團還原過程的影響.結果表明:球團低導熱率和反應等效熱匯是影響還原過程的主要因素,罐中心區域和罐壁處的溫度和反應速率存在較大差值;還原初期傳熱為還原過程的主要控制因素,而反應后期化學反應為主要控制因素;罐外換熱系數對還原過程影響不大,增強罐內傳熱是提高還原效率的有效途徑.

     

    Abstract: A coupled heat transfer and reaction kinetics model was established to study the lithium production efficiency and reduction rate of lithium production retorts. Numerical simulation of the pellet reduction process by this model was performed to obtain the time distributions of pellet temperature and reduction rate, and the effect of effective heat transfer coefficient outside the retorts on the pellet reduction process was analyzed. It is found that the low thermal conductivity of pellets and the chemical reaction equivalent heat sink are the main factors affecting the pellet reduction process. In the beginning of the reaction, heat transfer is the main controlling factor, but in the later, reaction kinetics is the controlling factor. The effective heat transfer coefficient outside the retorts has less influence on the pellet reduction process. Enhancing the heat transfer coefficient inside the retorts is an effective way to improve the production efficiency.

     

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