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ODS-310合金的高溫氧化行為

High temperature oxidation behavior of ODS-310 alloy

  • 摘要: 采用靜態氧化增重實驗及掃描電鏡、能譜分析和X射線衍射分析等手段,研究了ODS-310合金在高溫環境下的氧化行為,分析了氧化層的形貌、成分和物相,并對其高溫氧化動力學曲線進行擬合.實驗發現各個溫度下的氧化動力學曲線均基本符合拋物線規律.在700℃和900℃氧化100 h以后,ODS-310合金均表現出優異的抗氧化性能.但是,當氧化溫度為1100℃時,氧化層厚度明顯增厚,而且氧化層有疏松和不連續的現象,不利于氧化層對基體的保護.氧化程度隨著氧化溫度的提高和氧化時間的延長而加劇.通過能譜和X射線衍射綜合分析可知氧化層的物相為Cr2O3.

     

    Abstract: The high temperature oxidation behavior of oxide dispersion strengthened 310 (ODS-310) alloy was investigated by oxidation test. The morphology, composition and phase of the oxidation layer were analyzed by scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. It is found that the oxidation kinetic curves at all the temperatures approximately obey the parabolic law. After oxidizing at 700 and 900℃ for 100 h, the alloy shows a good resistance to oxidation. But after oxidizing at 1100℃, the oxide layer becomes thicker with the phenomenon of porosity and discontinuousness, which is harmful to the oxidation resistance. The oxidation degree of the alloy increases with the rising of temperature and the prolonging of time. Energy dispersive spectroscopy and X-ray diffraction analysis results indicate that the phase of the oxide layer is Cr2O3.

     

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