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Cr32Ni7Mo3N特級雙相不銹鋼的空蝕行為

Cavitation erosion behavior of Cr32Ni7Mo3N hyper duplex stainless steel

  • 摘要: 利用磁致伸縮空蝕試驗機對Cr32Ni7Mo3N特級雙相不銹鋼在蒸餾水和人工海水中進行了空蝕實驗,并采用掃描電鏡跟蹤觀察了經不同時間段空蝕后試樣的形貌.通過測量失重繪制了材料的累積失重量和失重率曲線.經電化學工作站測量了材料在靜態與空蝕條件下的極化曲線和腐蝕電位變化.對比分析了Cr32Ni7Mo3N與SAF2205雙相不銹鋼在人工海水的抗空蝕能力.結果表明:Cr32Ni7Mo3N特級雙相不銹鋼空蝕破壞首先在鐵素體薄弱區以及鐵素體和奧氏體相界發生,并向鐵素體內擴展,鐵素體發生解離斷裂脫落;奧氏體隨著空蝕的進行,滑移線增多,顯微硬度值增加,且人工海水中奧氏體顯微硬度值比在蒸餾水中的高;鐵素體大面積破壞后,奧氏體才失穩產生延性斷裂脫落,奧氏體的存在延緩了破壞在整個材料表面上的擴展.空蝕與腐蝕交互影響導致材料在人工海水中加速破壞.Cr32Ni7Mo3N特級雙相不銹鋼在人工海水中的抗空蝕能力優于SAF2205雙相不銹鋼.

     

    Abstract: The cavitation erosion behavior of Cr32Ni7Mo3 N hyper duplex stainless steel in both distilled water and artificial seawater was investigated by a magnetostrictive-induced cavitation facility. The micrographs of damaged surfaces after cavitation for different intervals of time were observed by scanning electron microscopy(SEM). The cumulative mass loss curves and cumulative mass loss rate curves of specimens were drawn by measuring the weight loss. The polarization curves and free-corrosion potentials of specimens were measured by electrochemical workstation in the static state and in the cavitation erosion condition. A comparison of cavitation erosion resistance was performed between the material and SAF2205 steel in artificial seawater. The results show that cavitation damage firstly occurs in the ferrite weak areas and ferrite-austenite phase boundaries,then gradually expands to the ferrite phase,and the ferrite phase dissociates off at last. Its failure mode is cleavage brittle fracture. As the cavitation erosion time prolongs,the austenite phase microhardness value increases because of slip lines generating more. During the entire cavitation,the microhardness value of the austenite phase in artificial seawater is higher than that in distilled water. When the ferrite phase is largely destroyed,austenite phase damage begins to happen and drop off. Its failure mode is ductile failure. So the existence of austenite delays fracture expanding to the entire material surface. In artificial seawater,the interaction of both cavitation erosion and corrosion leads to material failure acceleration,and the cavitation erosion resistance of Cr32Ni7Mo3 N steel is better than that of SAF2205 steel.

     

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