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垂直穩恒磁場下Fe-納米Si顆粒復合電沉積

Electrodeposition of Fe-nano-Si particle composite coatings in a perpendicular static magnetic field

  • 摘要: 在垂直穩恒磁場中采用納米復合電沉積法制備Fe-Si復合鍍層.研究了磁場強度和電流密度對陰極電流效率和鍍層Si顆粒含量的影響規律,并采用掃描電子顯微鏡和能譜對所得鍍層進行分析.施加垂直磁場后,隨著磁場強度增大,陰極電流效率呈現先上升后下降的趨勢;鍍層Si顆粒質量分數在0.2T達到最大值20.17%,比無磁場下提高了10.4%;鍍層表面形貌也發生顯著變化,多處形成"山脊","山脊"延伸方向與磁流體力學效應方向一致,分布數量和延伸長度與磁場強度成正比.由于磁流體力學效應,施加磁場還改變了鍍層表面氣孔形貌,促進氫氣的析出.

     

    Abstract: Fe-Si composite coatings were prepared by nano-composite electroplating in a static magnetic field parallel to the electrode surface. The effects of magnetic flux density and current density on the cathode current efficiency and silicon content in the coatings were studied. The coatings were characterized by scanning electron microscopy and energy dispersive spectrometry. It is found that the cathode current efficiency first increases and then decreases with increasing magnetic flux density. The mass fraction of silicon in the coatings reaches its maximum value of 20. 17% at 0. 2 T, which increases by 10. 4% compared with that without any magnetic field. In addition, the smooth surface morphology of the coatings turns into "mountain ranges", whose directions are the same to the direction of magnetohydrodynamic convection (MHD). More and longer "mountain ranges" appear with increasing magnetic flux density. Owing to MHD effect, the magnetic field also influences the surface morphology of hydrogen pores and promotes the evolution of hydrogen.

     

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