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純銅和電鍍銅包鋼在大港土壤中的初期腐蝕行為

Initial corrosion behavior of pure copper and electroplating copper-clad steel in Dagang soil

  • 摘要: 通過實驗室的實土埋樣實驗(30 d)、極化曲線、交流阻抗譜(EIS)測試和失重法對純銅和電鍍銅包鋼在大港實土中的初期腐蝕行為進行了研究.在腐蝕的初期階段,純銅的平均腐蝕速率略低于電鍍銅包鋼,它的耐土壤腐蝕性能略好;純銅和電鍍銅包鋼的腐蝕機制存在一定的差異,純銅的腐蝕行為受擴散控制影響較大.

     

    Abstract: The initial corrosion behaviors of pure copper and electroplating copper-clad steel in Dagang soil were investigated by burying tests in lab for 30 d, combining polarization curves, electrochemical impedance spectroscopy (EIS), and weight-loss method. It is found that during the initial stage of the corrosion process, the average corrosion rate of pure copper is slightly lower than that of electroplating copper-clad steel, and pure copper exhibits a higher corrosion resistance than electroplating copper-clad steel. There are some differences in the corrosion mechanism between pure copper and electroplating copper-clad steel. The corrosion behavior of pure copper is mainly affected by diffusion control.

     

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