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類金剛石薄膜在錐形納米壓頭作用下的斷裂分析

Fracture analysis of diamond-like carbon films under conical nanoindentation

  • 摘要: 硬薄膜往往具有較脆的特性,在過載時易發生脆性斷裂.本文研究了硬薄膜/軟基體在錐形納米壓頭作用下的斷裂模式.利用等離子體化學沉積法在聚二醚酮基體上沉積生成類金剛石薄膜.使用納米壓痕法對其進行實驗研究,實時記錄納米壓頭壓入樣品過程中所受的載荷以及位移.載荷位移曲線中有若干間斷點,代表著裂紋的形成和擴展.壓痕實驗完成后,通過掃描電子顯微鏡和聚焦離子束觀察發現,類金剛石薄膜壓痕處出現規則的貫穿厚度的環形裂紋和徑向裂紋.最后,利用有限元法分析了硬薄膜/軟基體在錐形壓頭作用下的應力分布,通過cohesive單元模擬環形裂紋的起始和擴展.結果表明:環形裂紋是由薄膜表面較高的徑向拉應力引起的,較高的徑向拉應力發生于壓頭和薄膜表面接觸區域的外側;徑向裂紋則是由薄膜在界面附近較大的拉應力引起的.并且,各圈環形裂紋的半徑基本呈線性遞增,這和實驗觀測基本相符.

     

    Abstract: This article reports fracture in hard films on a soft substrate under conical indentation. A diamond-like carbon (DLC) film was deposited onto a poly-ether-ether-ketone (PEEK) substrate using plasma chemical vapor deposition. Nanoindentation was performed on the film surface, in the meanwhile, load and depth data were recorded, and ‘pop-in’, correlated with crack formation, was found in load-depth curves. Ring cracks and radial cracks in the film were observed by scanning electron microscopy and focused ion beam method after indentation. Finally, finite element analysis using cohesive elements was conducted to study the stress distribution of the hard film/soft substrate. It is found that ring cracks in the thin film are induced by high tensile radial stress on the film surface outside the contact region of the indenter, while radial cracks are caused by high tensile stress on the thin film near the interface. The results also show that the radius of ring cracks increases with the number of ring cracks, which agrees well with experimental observations.

     

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