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Fe—Cr—O體系碳還原產物的形態

Morphology of products from the carbon reduction of Fe-Cr-O systems

  • 摘要: 研究了不同溫度和不同時間條件下C還原Fe-Cr-O體系所得產物的形態,樣品主要包括FeCr2O4+C和Fe2O3+2Cr2O3+C兩種體系.兩種樣品的還原度均隨溫度升高而升高,反應接近平衡時還原率均在90%以上.C還原FeCr2O4和Fe2O3-Cr2O3的過程大致相同,且最終還原產物基本組成均為Fe-Cr-C合金和金屬碳化物(主要為Cr7C3).針對最終還原產物中Fe-Cr-C合金和金屬碳化物的含量提出了一種估算方法,其估算結果與理論計算結果基本吻合.結果顯示,最終產物中Fe-Cr-C合金量隨溫度升高而升高,碳化物含量隨溫度升高而降低,且不同溫度條件下所獲得的Fe-Cr-C合金成分不同.

     

    Abstract: The morphology of the reduction products of Fe-Cr-O systems by C at different temperatures and time intervals was studied in this paper. The samples include two systems of FeCr2O4 +C and Fe2O3 +2Cr2O3 +C. It is found that the reduction degrees of the two samples increase with increasing temperature, and the reduction degree can be above 90% when the reaction is close to balance. The reduction processes of FeCr2O4 and Fe2O3-Cr2O3 are similar and the final reduction products are composed of Fe-Cr-C alloys and metal carbides (mainly Cr7C3). A method was proposed to estimate the contents of Fe-Cr-C alloys and metal carbides in the final reduction products, and the estimated results agree with the calculated data. It is shown that the content of Fe-Cr-C alloys increases while the content of metal carbides decreases with increasing temperature, and the composition of Fe-Cr-C alloys varies with temperature.

     

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