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濃硫酸中904L不銹鋼焊接接頭的耐蝕性能

Corrosion resistance of 904L stainless steel welding joints in concentrated sulfuric acid

  • 摘要: 采用動電位極化曲線和電化學阻抗譜研究了904L不銹鋼基體和焊接區在濃硫酸溶液中的腐蝕行為,并簡要分析其腐蝕機理.實驗結果表明:焊接區和基材的陰極極化曲線均為氫還原反應過程,而陽極極化曲線則有較大的差異.焊接區相對于基材,其自腐蝕電位降低且陽極電流增大,焊接對陽極反應起促進作用.904L不銹鋼基體和焊接區的腐蝕主要由電化學反應步驟控制,兩者的Nyquist圖特征相似,均由單一的容抗弧構成,有一個時間常數.基體的耐蝕性能優于焊接區.

     

    Abstract: Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) were used to investigate the corrosion resistance of 904L stainless steel welding joints in concentrated sulfuric acid, and the corrosion mechanisms were analyzed in brief. Experimental results show that there are no significant changes in cathodic polarization curves of the weld zone and the substrate, both of them are hydrogen reduction reaction process while an opposite trend is seen upon the anodic polarization curves. Compared with the substrate, the corrosion potential of the wilding zone decreases while the anode current increases. Welding contributes to the anode reaction. The corrosion of the substrate and the weld zone is mainly controlled by the electrochemical step. Both Nyquist graphs are similar, which are composed of a single capacitive reactance arc, having a time constant. The corrosion resistance of the substrate is superior to the weld zone.

     

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