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鐵礦粉與CaO同化反應性能的表征方法

Characterization method for assimilation reactions between iron ores and CaO

  • 摘要: 為解決在研究鐵礦粉與CaO進行同化反應時通常采用最低同化溫度這一終點體系指標來表征,而沒有考慮同化反應速度和升溫速率的缺陷以及采用多個指標來表征同化反應溫度和速度在使用上的不便,本文充分利用鐵礦粉在高溫同化反應過程中獲得的數據和范特霍夫規則,提出了量綱為1的同化反應特征數.該特征數包括同化反應速度、升溫速率、同化溫度和溫度對同化反應速度的影響,可用來表征鐵礦粉與CaO的同化過程中鐵礦粉的同化溫度、同化反應時間、同化反應結束溫度等性能,并以燒結過程中的實際溫度作為基準.該特征數綜合了鐵礦粉與CaO在同化反應過程中各重要信息,可以更全面地反映鐵礦粉與CaO的同化反應性能.對兩種方法得到的結果進行了比較,發現僅考慮最低同化溫度這一終點指標時得到的結果相近,而采用同化反應特征數可以進一步細分出不同鐵礦粉同化反應性能的差異.

     

    Abstract: The lowest assimilation temperature is usually used as a terminal system index to characterize assimilation reactions between iron ores and CaO. However, this characterization does not take into account assimilation speed and heating rate. In order to adopt several indexes to evaluate the characteristics of the assimilation reactions, this article introduces an assimilation characteristic parameter by adopting the Van't Hoff's law and making full use of data obtained in the high temperature assimilation process of iron ores. The characteristic parameter, which considers assimilation speed, heating rate, assimilation temperature and the effect of temperature on assimilation speed, can characterize assimilation reactions between iron ores and CaO, including assimilation starting temperature, assimilation time, assimilation finishing temperature, etc. Moreover, it is based on the practical production temperature of sintering ores. Because of integrating much more important information in the assimilation process of iron ores, this parameter can comprehensively reflect the assimilation properties of iron ores. Although the same or similar results are obtained by the two methods, com-pared with the conventional method by only considering the lowest assimilation temperature, the new method can find out assimilability differences of different iron ores in further analysis.

     

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