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陰極弧離子鍍TiAlSiN涂層摩擦與磨損行為

Friction-wear behaviors of TiAISiN coatings prepared by cathodic arc ion plating

  • 摘要: 采用陰極弧離子鍍法在GH4169合金表面制備了TiAlSiN涂層,通過掃描電鏡和能譜儀分析了其表面和界面的形貌和能譜,用輪廓儀測試了涂層表面粗糙度.在往復式摩擦磨損試驗機上進行了涂層摩擦與磨損實驗,通過能譜儀分析了涂層表面磨損后點能譜和面能譜,考察了TiAlSiN涂層的摩擦因數和磨損性能,對其磨損機理進行了討論.實驗結果顯示涂層表面組織結構較為致密,表面粗糙度為194.57 nm;涂層主要成分為Ti、Al、Si和N元素,Si原子細化了TiN和AlN晶粒;涂層結合界面發生了化學反應和成分的相互擴散,其結合形式為化學結合;涂層摩擦因數平均值為0.493,磨損形式為磨粒磨損;磨損痕跡面掃描結果表明,磨損后Al和Ti形成的氮化物減少,Si和N原子無明顯的減少現象,涂層耐磨性增強主要依賴于Si和N形成的化合物.

     

    Abstract: TiAlSiN coating was prepared on the GH4169 alloy surface by cathodic arc ion plating, the morphologies and energy spectra of its surface and interface were analyzed by scanning electron microscopy and energy dispersive spectroscopy, respectively, and the surface roughness was tested by profilometry. Friction and wear test of the coating was performed on a reciprocating friction testing machine, the point energy spectra and plane energy spectra after wear were analyzed by energy dispersive spectroscopy, the friction coefficient and wear property of the coating were studied, and the wear mechanism was discussed. Experimental results show that the structure of the coating surface is compact and the surface roughness is 194.57 nm. The coating is mainly composed of Ti, Al, Si and N elements, and the grains of TiN and AlN are refined by Si atoms. Chemical reactions and mutual diffusion of elements occur in the coating interface, and the combining form is chemical bonding. The average friction coefficient of the coating is 0.493, and the wear form is abrasive wear. The plane scanning results of wear traces indicate that Al and Ti nitrides in the coating decreases after wear, Si and N atoms have no significant reduction, and the increase in wear resistance of the coatings is mainly dependent on the compound formed by Si and N atoms.

     

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