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利用石灰干化污泥制備水泥對水泥性能的影響

Effect of utilizing lime mediated sludge to produce cement on cement performance

  • 摘要: 使用石灰干化污泥作為水泥原料的部分代替品制備水泥,石灰干化污泥質量分數變化范圍在0-30%時探討了石灰干化污泥的加入對水泥各項性能的影響.結果表明:石灰干化污泥以15%的加入量摻入生料后,可以明顯改善水泥熟料的煅燒性能、礦物相晶體結構及形貌,并且能夠顯著增強水泥強度.當石灰干化污泥摻量繼續增加后,其對于水泥性能的改善作用逐漸下降,當添加量達到30%時制得的水泥性能與未加入污泥的水泥已相差不大.毒性浸出實驗結果顯示:加入石灰干化污泥后,熟料和水泥的重金屬含量較未加入污泥時高,但浸出量很低,浸出液中Cu、Zn、Pb、Cr和Ni的質量濃度均在lmg·L-1以下,遠低于國家標準GB5085.3-2007,不會產生二次污染.

     

    Abstract: Lime mediated sludge Was Used as partial replacement for cement raw materials to produce cement. The adding amount of lime mediated sludge ranges from 0 to 30%. The influence of lime mediated sludge on cement performance was investigated. It is shown that adding 15% of lime mediated sludge into cement raw materials can significantly improve the calcining performance, the mineral phase crystal structure and the clinker's morphology, and the cement strength is also remarkably enhanced. The improvement capability of lime mediated sludge gradually declines with the increase of lime mediated sludge. When 30% of lime mediated sludge is added, the properties of the obtained cement are similar to those without adding sludge. Toxicity characteristic leaching test results indicate that after lime mediated sludge addition, heavy metalconcentrations in clinker and cement are higher than those in clinker and cement without lime mediated sludge, while the leaching concentrations are very low, Cu, Zn, Pb, Cr and Ni contents in the leachate are all below 1 mg·L-1, which canmeet the People's Republic of China Standard GB 5085.3-2007, with no risks of secondary pollution.

     

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