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Al脫氧鋼中氧化物對MnS析出的影響

Effect of oxides on MnS precipitation in aluminum-deoxidized steel

  • 摘要: 使用10 kg真空感應爐Al脫氧冶煉較高S含量超低氧高強度鋼,鋼中TO降到0.0010%,S的質量分數為0.0190%.采用ASPEX explorer全自動掃描電鏡對鋼中非金屬夾雜物進行檢測,發現98%非金屬夾雜物都是彌散分布的MnS和MnS+Al2O3復合夾雜物.MnS夾雜物棱角分明,從形貌特征來看應屬于第Ⅲ類硫化物.MnS+Al2O3復合夾雜物以Al2O3為核心,外層包裹MnS,其數量約占9%~32%;作為核心的Al2O3平均直徑為1.5μm.其生成過程可描述為:凝固過程中,小尺寸Al2O3被推至固液兩相區,而選分結晶作用使得鋼中的Mn和S在凝固前沿富集,并以Al2O3作為異質形核質點析出MnS夾雜物.對凝固過程中Al2O3的推動和捕獲行為進行了相關計算.計算結果表明:直徑小于4μm的Al2O3可被推動,并作為MnS的異質形核質點.

     

    Abstract: High strength steel with slightly higher S content, deoxidized by aluminum, was smelted in a vacuum induction furnace of 10 kg capacity. Total oxygen in the steel was 0.0010%, and the S content reached 0.0190%. An ASPEX explorer auto-scanning electron microscope (SEM) was used to detect nonmetallic inclusions in the steel. It is found that 98% of the inclusions are dispersed MnS and MnS+Al2O3 complex inclusions. The shape of MnS inclusions is angular, belonging to type III. Al2O3 inclusions, with an average diameter of 1.5 μm, acting as nucleation for MnS precipitation, generate wrapped inclusions of MnS+Al2O3, and they rank 9% to 32% of the total inclusions. The formation process of MnS+Al2O3 can be described as follows:small size Al2O3 inclusions are pushed to liquid phase at melt steel solidification, and then Al2O3 inclusions work as the sites of MnS inclusion precipitation due to Mn and S microsegregation. However, related calculations about the pushing and engulfment behavior of Al2O3 inclusions were carried out. The calculated results indicate that Al2O3 inclusions with the size smaller than 4 μm are pushed in liquid steel, acting as heterogeneous nucleation for the formation of MnS inclusions.

     

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