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Fe對Ni-Mn-Ga形狀記憶合金相變和力學性能的影響

Effect of Fe addition on the martensitic transformation behavior and mechanical properties of Ni-Mn-Ga shape memory alloys

  • 摘要: 研究了Fe含量對Ni56Mn25-xFexGa19(x=0~10)合金的微觀組織結構、相變行為、力學性能和記憶特性的影響規律.當x ≤ 4時,Ni56Mn25-xFexGa19合金仍然保持著單一的四方結構馬氏體相;當x ≥ 6時,合金呈現為馬氏體相和面心立方γ相組成的雙相結構.相對于馬氏體相,γ相為富Ni和富Fe相,其含量隨Fe含量的增加而增加.隨著Fe含量增加,合金的馬氏體相變溫度逐漸降低,其峰值溫度從x=0時的356℃降低至x=10時的170℃,這主要歸因于馬氏體相尺寸因素和電子濃度的綜合作用.通過添加Fe替代Mn在合金中引入的γ相可提高合金的強度和塑性,但最大形狀記憶回復應變從x=0時的5.0%降低到x=6時的2.0%.

     

    Abstract: The microstructure, martensitic transformation behavior, mechanical properties and shape memory characteristics of Ni56Mn25-xFexGa19 (x=0-10) shape memory alloys were investigated by optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, differential scanning calorimetry, and compression testing. A single phase of martensite with tetragonal structure is observed in the alloys with x ≤ 4, but dual phases with martensite and face-centered cubic γ phase are present when x ≥ 6. Compared with martensite phase, γ phase is rich in Ni and Fe, and its volume fraction increases with increasing Fe content. The martensitic transformation peak temperature decreases from 356℃ for x=0 to 170℃ for x=10, which is attributed to the comprehensive effect of the tetragonality and electron concentration of martensite. The introduction of γ phase by substituting Fe for Mn can greatly improve the strength and plasticity of the alloys. However, the shape memory strain drops from 5.0% for x=0 to 2.0% for x=6.

     

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