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稀土對T91耐熱鋼動態再結晶行為影響

Effect of rare earths on the recrystallization behavior of T91 heatresistant steel

  • 摘要: 采用Gleeble-1500熱/力模擬試驗機進行壓縮試驗,研究了不同變形條件下微量稀土對T91耐熱鋼動態再結晶行為的影響.分析繪制了稀土加入前后實驗鋼的真應力-真應變曲線、再結晶-溫度-時間圖、再結晶圖及功率耗散圖,并計算了高溫下實驗鋼的再結晶激活能.在變形溫度為850~1100℃,變形速率為0.004~10 s-1變形條件下,變形溫度越高和變形速率越低,動態再結晶越容易發生.稀土加入會產生固溶強化,稀土元素與碳原子發生交互作用,且在晶界處或晶界附近偏聚,使變形抗力與峰值應變均增大,再結晶激活能由354.6 kJ·mol-1提高到397.2 kJ·mol-1.另外,稀土會顯著推遲再結晶發生時間,擴大再結晶的時間間隔,推遲再結晶動力學過程.

     

    Abstract: The effect of rare earths on the dynamic recrystallization behavior of T91 heat-resistant steel under different deformation conditions was investigated on a Gleeble-1500 thermo-mechanical simulator. The true stress-strain curves, recrystallization-temperature-time (RTT) map, dynamic recrystallization map and power dissipation map were drawn for the steels with and without rare earths. The recrystallization activation energies of these two kinds of steels at elevated temperatures were also calculated in this paper. It is found that under the deformation condition of the temperature of 850 to 1100℃ and the strain rate of 0.004 to 10 s-1, dynamic recrystallization happens at higher temperatures and lower strain rates. Rare earths dissolve in the matrix, resulting in solid solution strengthening. Rare earth elements interact with carbon and segregate at grain boundaries or around the matrix, leading to the increasing of peak stress and peak strain as well as the improvement of recrystallization activation energy from 354.6 kJ·mol-1 to 397.2 kJ·mol-1. In addition, rare earths delay the starting time of recrystallization greatly, extend the time interval of recrystallization, and postpone the recrystallization kinetic process.

     

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