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汽車大梁鋼中第二相粒子析出行為

Precipitation behavior of secondary phases in automobile beam steel

  • 摘要: 運用熱動力學理論和Oswald熟化理論研究了不同氮含量汽車大梁鋼中第二相粒子的析出和熟化行為.研究發現鋼中N含量的增加會促進V(C,N)在奧氏體中析出從而細化鐵素體晶粒,當氮的質量分數增至4.2×10-4時鐵素體晶粒尺寸能細化至4.7μm.形核率–溫度曲線和析出–溫度–時間曲線表明氮含量的增加可以擴大奧氏體區中最大形核率的溫度范圍,氮的質量分數由5.5×10-5增至4.2×10-4時其最快析出的鼻點溫度由840℃上升至968℃.透射電鏡觀察顯示氮含量的增加明顯降低析出V(C,N)粒子的尺寸.VN在奧氏體中的Oswald熟化速率計算表明熟化速率隨溫度的降低不斷減少,同時增加N含量還可以有效降低析出粒子的熟化速率,從而抑制沉淀析出的第二相粒子的熟化長大過程.

     

    Abstract: The precipitation and ripening behavior of secondary phases in automobile beam steel with different nitrogen contents were investigated by the thermo-kinetic theory and the Ostwald ripening theory. It is found that increasing the content of nitrogen in the steel can promote the precipitation of V(C,N) in austenite, thus the ferrite grains are greatly refined, and the ferrite grain size is decreased to 4.7μm when the content of nitrogen increases to 4.2×10-4. The curve of nucleation rate to temperature calculated by the thermodynamic theory shows that nitrogen can effectively expand the temperature zone of the biggest nucleation rate, and the precipitation-temperature-time curve demonstrates that the shortest incubation temperature can rise from 840℃ to 968℃ when the content of nitrogen increases from 5.5×10-5 to 4.2×10-4. Transmission electron microscopy observations reveal that the size of precipitated V(C,N) is effectively decreased with the increasing content of nitrogen. The calculated Ostwald ripening rate of VN in austenite indicates that the ripening rate weakens with the temperature dropping, and moreover increasing the content of nitrogen also can decrease the ripening rate to inhibit the ripening growth of the precipitated secondary phases.

     

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