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鈦合金化過程對鋼液潔凈度的影響

Effect of ferro-titanium alloying process on steel cleanness

  • 摘要: 重點考察了Ti合金化過程中影響Ti收得率的主要因素,并對比分析了Ti合金化前后夾雜物的物相變化及夾雜物的去除效果.控制氧活度aO<350×10-6,Al、Ti合金加入時間間隔大于3 min,可以保證Ti收得率>85%;當aO>350×10-6時,需控制Al、Ti合金加入時間間隔為5 min以上.相同aO和Als情況下,延長Al、Ti加入時間間隔可以有效提高Ti收得率.RH處理過程中,鋼包內當量直徑>200μm的Al2O3夾雜物在5 min內基本可以上浮去除,但相同尺寸的A-Ti-O復合夾雜的去除時間要比Al2O3長1~2 min.Ti合金加入后,Al2O3夾雜物周圍會形成Al-Ti-O的復合夾雜,這些夾雜物的形成降低Ti的收得率.

     

    Abstract: The main factors were studied which influence the titanium yield during a ferro-titanium alloying process. The inclusion phases and removal effect were comparatively analyzed before and after ferro-titanium alloying. When controlling the activity of oxygen (ao) before deoxidation below 350×10-6, the interval time between Al and Ti addition above 3 min can guarantee the titanium yield above 85%. With ao above 350×10-6, the interval time between Al and Ti addition should be extended more than 5 min. Extending the interval time between Al and Ti addition can improve the titanium yield at the same ao and Als. During RH refining, Al2O3 inclusions with the equivalent diameter above 200 μm can float and be removed within 5 min, but the removal time of AI-Ti-O inclusions with the same size is 1 to 2 min more than pure Al2O3. Al-Ti-O complex inclusions form around Al2O3 after the titanium alloy being added into the melt, and the titanium yield decreases due to the formation of these inclusions.

     

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