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基于均勻形核的金屬液滴凝固過程

Solidification of metallic droplets based on homogeneous nucleation

  • 摘要: 研究了均勻形核的金屬液滴凝固過程,應用漸近分析法求得金屬液滴內晶核生長數學模型的漸近解,分析了表面張力、界面動力學參數、初始晶核尺寸和過冷度對晶核界面生長速度、晶核半徑以及液滴凝固時間的影響.在一定的過冷條件下,表面張力和界面動力學參數顯著減緩了晶核界面生長速度.在凝固開始的很短時間內晶核界面生長速度迅速上升,當速度上升到最大值后,隨著晶核半徑的增大,界面生長速度逐漸減慢,表面張力和界面動力學參數對晶核生長速度的作用也逐漸減小.過冷度越大,液滴凝固時間越短.經過在開始的瞬變凝固階段之后,溫度場從設定的初始分布迅速地調整為由過冷度、表面張力、界面動力學參數等所確定的特定溫度分布.

     

    Abstract: The solidification of metallic droplets based on homogeneous nucleation is studied by a mathematical model of nucleus growth in metallic droplets. An asymptotic solution to the model is obtained by the asymptotic analysis method. The effects of surface tension, interface kinetic parameter, initial nucleus size, and undercooling on the growth rate, radius, and solidification time of the nucleus are analyzed on the basis of the asymptotic solution. It is found that surface tension and interface kinetics parameter significantly decrease the growth rate of the nucleus under a certain undercooling condition. The growth rate of the nucleus rapidly rises in the initial short period of solidification. After the growth rate of the nucleus reaches its maximum~ it gradually descends with the increase of nucleus radius. In the meantime, the effects of surface tension and interface kinetic parameter on the growth rate of the nucleus decline gradually. With the increase of undercooling, the solidification time of the droplet decreases. After transient solidification within the initial short period, the temperature distribution in the droplet is rapidly modified from some initial distribution to a certain temperature distribution determined by undercooling, surface tension, interface kinetic parameter, etc.

     

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