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磁場作用下煤系針狀焦的制備與電化學性能

Preparation of coal-based needle coke under magnetic fields and its electrochemical properties

  • 摘要: 以除去喹啉不溶物的煤瀝青為原料,在自制的載磁反應釜中制備針狀焦.通過改變體系聚合反應最大壓力及最高溫度,對針狀焦制備過程中施加磁場后中間相形成階段的溫度、體系最大壓力等工藝條件進行了探討,研究了不同條件下制備的針狀焦的結構與電化學性能.采用掃描電子顯微鏡、X射線衍射儀表征產物的結構特點;采用循環伏安法及電化學阻抗等分析方法表征了不同條件下制備的針狀焦的電化學性能.在磁場作用下,體系最大壓力為0.4 MPa、體系最高聚合溫度為520℃時制備的針狀焦具有最佳的結構及電化學性能.

     

    Abstract: Medium temperature coal tar pitch with quinoline insoluble compounds removed was used as the raw material. Coal-based needle coke was prepared in a home-made reactor with a magnetic field. The temperature and the maximum pressure for the formation of the mesophase under the magnetic field were discussed during the preparation of the needle coke. The structure and electrochemical properties of the needle coke prepared under different conditions were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). Under the action of the magnetic field, when the maximum pressure is 0.4 MPa and the maximum temperature is 520℃, the needle coke has the best structure and electrochemical properties.

     

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