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不同脫氧方式對鋼中夾雜物的影響

Effect of deoxidation methods on inclusions in steel

  • 摘要: 為控制鋼液中氮含量,實驗了兩種不同脫氧方式:(Ⅰ)出鋼過程加Al進行強脫氧;(Ⅱ)出鋼時不加Al,加入Si-Mn合金進行弱脫氧,在LF進站再喂入Al線進行強脫氧.借助氣體分析儀和掃描電鏡對不同脫氧方式下鋼中氧氮含量和夾雜物進行了分析.兩種不同脫氧方式得到最終產品的全氧含量幾乎一致,但方式(Ⅱ)對控制氮含量更為有利,可以使氮的質量分數降低約5×10-6;兩種不同脫氧方式對最終產品中夾雜物的類型和尺寸影響不大,均為球狀的CaS和CaO-MgO-Al2O3夾雜物.文中還推斷出了采用Si-Mn弱脫氧時鋼中夾雜物的生成過程.

     

    Abstract: In order to control the nitrogen content of liquid steel, two different deoxidation methods were applied:(Ⅰ) Al blocks were added for deoxidation when tapping; (Ⅱ) Si-Mn alloys without Al were added for deoxidation at first when tapping, and then Al wires were fed at the LF station. The oxygen content, nitrogen content and inclusions in steel deoxidized by the two methods were analyzed by gas analyzer and scanning electron microscopy (SEM). It is found that the total oxygen content of the final product is almost the same with the two deoxidation methods, while the method (Ⅱ) is more advantageous to control the nitrogen content and by using the deoxidation method the nitrogen content can decrease by about 5 × 10-6. Both the deoxidation methods affect little the type and size of inclusions in the final product, and most of the inclusions are globular CaS and CaO-MgO-Al2O3 inclusions. The formation process of inclusions during Si-Mn deoxidation was inferred according to SEM observations and thermodynamics.

     

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