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改性活性炭纖維負載錳鈰復合氧化物低溫選擇性催化還原脫硝

Low-temperature SCR denitrification with manganese-cerium composite oxide supported on modified ACF

  • 摘要: 采用Ce-MnOx/ACFN對煙氣進行低溫選擇性催化還原脫硝實驗,分別考察了活性炭纖維(ACF)改性、Ce-MnOx負載量和Ce/Mn摩爾比以及操作條件對脫硝效率的影響.在70~110℃條件下,Ce-MnOx/ACFN作為選擇性催化還原脫硝的催化劑具有良好的活性,其脫硝效率隨煙氣溫度升高而升高.催化劑載體活性炭纖維經硝酸改性后脫硝效率有明顯提高.隨著Ce-MnOx負載量增加和Ce/Mn摩爾比增加,脫硝效率先升高后降低.隨著入口煙氣NH3/NO摩爾比增加,脫硝效率先升高后趨于穩定.當入口煙氣中水蒸氣體積分數大于8%時,脫硝效率隨其增加而降低.

     

    Abstract: The low-temperature selective catalytic reduction (SCR) denitrification of a flue gas was carried out with Ce-MnOx/ACFN. The denitrification efficiencies were studied by modifying the activated carbon fibers (ACF) and changing the Ce-MnOx loading capacity, Ce/Mn molar ratio and operating conditions respectively. Ce-MnOx/ACFN as a SCR denitrification catalyst has good activity at 70-110℃. The denitrification efficiency increases with rising temperature, and it improves obviously after the ACF is modified by nitric acid. With the increasing of Ce-MnOx loading capacity and Ce/Mn molar ratio, the denitrification efficiency increases firstly and then decreases; but with the increasing of NH3/NO molar ratio in the inlet flue gas, it increases firstly and then tends to be stable. When the volume fraction of vapor in the inlet flue gas is above 8% the denitrification efficiency decreases with the vapor volume fraction increasing.

     

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