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煉鐵用生物質焦的制備及其性能

Preparation and properties of biomass char for ironmaking

  • 摘要: 采用兩種不同的升溫制度對生物質進行碳化,碳化溫度選為300、400、500、600和700℃,保溫時間分別為30、60和90 min.利用掃描電鏡及熱重分析儀對所得生物質焦的成分、微觀結構及燃燒性能等進行分析,并研究了制備條件對生物質焦的產率及與CO2反應性的影響.結果表明,生物質焦具有與煤不同的典型管狀或片狀結構,其N、S、灰分、堿金屬含量及燃燒性能優于煤炭,適合用作煉鐵過程的還原劑和發熱劑,以替代部分煤粉和焦炭.綜合考慮,煉鐵用生物質焦的最佳制備條件是,采用恒溫加熱模式將生物質加熱至500℃進行碳化,并保溫30 min.

     

    Abstract: Raw biomass was carbonized by two different heating patterns to produce biomass char at 400, 500, 600 and 700℃ for 30, 60 and 90 min. The composition, microstructure, and combustibility of the derived biomass char were investigated by scanning electron microscopy (SEM) and thermogravimetric analysis (TG-DTG). The effects of preparing conditions on the biomass char's yield and reactivity for reacting with CO2 were studied. It is shown that the biomass char has typical duct structure or sheet structure, which is different from coal. The contents of N, S, ash and alkali metals in the biomass char are much lower, but its combustibility is better than coal samples, suitable for using as a reducing agent and a heating agent in ironmaking to partially replace coal and coke. The optimum preparing condition of biomass char for ironmaking is to carbonize raw biomass by a constant temperature heating pattern at 500℃ for 30 min.

     

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