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700℃以上超超臨界電站鍋爐過熱器管材用典型鎳基合金的平衡析出相規律

Equilibrium-phase precipitation behaviors of typical nickel-base alloys for 700℃ advanced ultra-supercritical boiler tubes

  • 摘要: 利用熱力學計算軟件Thermo-Calc及鎳基合金數據庫,計算了三種700℃以上超超臨界電站用過熱器管道材料Inconel740、Inconel617和GH2984合金的熱力學平衡相圖,并對比了三種材料主要析出相的析出行為.計算結果表明:三種合金主要的析出相包括γ、γ'、碳化物、σ、η、δ、μ及α-Cr等,凝固過程中Mo、Nb和Ti元素偏析嚴重,會降低合金的初熔點,因此后期均勻化退火處理十分重要.另一方面,750℃時Inconel740合金γ'相析出量大于另外兩種合金,并且Al和Ti含量對γ'相和η相析出行為有較大影響.碳化物的計算表明,Inconel617合金一次碳化物與另兩種合金不同,并且其二次碳化物的析出溫度范圍最大.GH2984合金中Fe含量較大時會導致σ相出現,對合金的性能產生不利影響.

     

    Abstract: Thermodynamic equilibrium phase diagrams of three candidate materials, Inconel740, Inconel617, and GH2984, for 700℃ advanced ultra-supercritical boiler tubes were calculated by Thermo-Calc software and nickel-base alloy databases. Precipitation behaviors of phases in the three alloys were investigated by comparison. There are similar equilibrium phases in the three alloys, including γ, γ', carbides, σ, η, δ, μ, and α-Cr. Serious segregations of Mo, Ti and Nb may occur during solidification based on the calculation, which would decrease the initial melting points of the three alloys; therefore the consequent homogenization treatment is quite important. On the other hand, the amount of γ' precipitated in Inconel740 is higher than that in the other two alloys at 750℃. Al and Ti contents can strongly effect the precipitation of γ' and η phases. The calculation of carbides indicates that primary carbides in Inconel617 are different from those in the other two alloys, and the precipitation temperature range of secondary carbides in Inconel617 is larger. The presence of σ in GH2984 alloy is harmful to the mechanical properties due to a higher Fe content.

     

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