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高鋁鋼鈣處理工藝熱力學研究

Metallurgy effect of calcium treatment in high grade pipeline steel

  • 摘要: 為了解決短流程生產高鋁鋼時水口堵塞的問題,對某廠鈣處理工藝前后的鋼液成分以及鋼液中的夾雜物進行了系統研究,并運用Bj?rkvall模型對其進行了熱力學分析.研究結果表明喂鈣量過大,鋼中S過高,則浸入式水口(SEN)堵塞物主要為CaS以及含有CaS較高的復合夾雜物.根據鋼液中的Al-Ca-S三元活度平衡圖可知,生產Als為0.32%~0.39%高鋁鋼時,為防止高鋁鋼澆注過程中生成CaS造成水口堵塞,鋼中Ca應控制在0.004 0%~0.008 5%,S應控制在0.002 0%以下.

     

    Abstract: In order to solve the nozzle clogging in the compact strip production (CSP) process of high-content aluminum steel,the steel composition and inclusions before and after the calcium treatment were analyzed,and thermomechanical analysis based on Bj?rkvall model was also carried out. The results show that theSandCaare both too high,as a result,CaS and high-content CaS inclusions are the main causes of the clogging. According to the Al-Ca-S equilibrium diagram,when the high-content aluminum steel, whoseAls is at 0.32% to 0.39%,is prepared,in order to prevent the formation of CaS in casting process,theSin steel should be controlled less than 0.002 0% andCain the molten steel should be controlled in the range of 0.004 0% to 0.008 5%.

     

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