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轉爐鐵水預處理脫磷實驗研究

Study on the dephosphorization of hot metal in converter

  • 摘要: 首鋼京唐公司采用轉爐鐵水預處理脫磷工藝作為潔凈鋼生產平臺,通過前期58爐冶煉實驗,摸索出一套適和京唐公司生產實際的操作工藝,并在造渣制度、吹煉模式、溫度控制等方面取得了重大突破,實現了穩定、高效生產低磷鋼、超低磷鋼的目標.脫磷爐終點磷的質量分數平均為0.017%,碳的質量分數為3.69%,脫磷爐終點平均溫度為1350℃,并有10爐鋼的脫磷爐終點磷的質量分數小于0.015%,最低為0.008%,達到了生產超低磷鋼的預脫磷要求.對實驗中影響脫磷效果的因素,如鐵水硅含量,脫磷爐終點溫度、終點碳含量、終渣堿度和氧化性等,進行了深入研究.分析表明當鐵水硅的質量分數小于0.45%時,可以達到比較好的脫磷效果;脫磷爐的脫磷效果隨終點溫度的升高而逐漸變差,但為保證脫碳爐有足夠的熱量,脫磷爐終點溫度控制范圍為1350~1380℃;脫磷爐合理的碳含量范圍應該在3.3%~3.8%之間;堿度控制在1.8~2.2即可滿足脫磷爐的脫磷效果;通過增加礦石加入量,保持較高槍位可以提高冶煉過程渣中(FeO)含量,提高脫磷爐的脫磷效率.

     

    Abstract: Dephosphorization treatment was utilized in the clean steel process in Shougang Jingtang Iron & Steel United Co. Ltd. Based on the first 58 heats tests,the practical operation process were established,especially for slag making,oxygen injecting,and temperature controlling. The stable and efficient method for low-P content and ultra-low-P content steel production was obtained. According to the experiments results,the average P content (mass fraction,so as the following) in the dephosphorization converter is 0.017%,the C content is 3.69%,and the converter terminal temperature is 1 350℃. Moreover,the P content of 10 heats is below 0.015% with the lowest content of 0.008%,which meets the requirement of ultra-low-P steel. The factors which can affect the dephosphorization process,such as silicon content,carbon content,converter terminal temperature,slag basicity,and oxidizability were investigated. The results demonstrate that when the silicon content is below 0.45%,dephosphorization is relatively more efficient. As the converter terminal temperature increases,the dephosphorization result becomes worse; however,to guarantee the temperature in the de-carbon converter,the dephosphorization converter terminal temperature is fixed at 1 350 to 1 380℃. The reasonable carbon content in the dephosphorization converter is 3.3% to 3.8%. To meet the dephosphorization requirement,the basicity (R) is controlled between 1.8 and 2.2. Enhancing the ore addition and keeping the higher lance position are suggested to increase the FeO content in slag to increase the dephosphorization efficiency.

     

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