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X70管線鋼在含CO2濕天然氣環境下腐蝕行為

CO2 corrosion behavior of X70 pipeline steel in wet gas environment

  • 摘要: 利用高溫高壓冷凝釜模擬油氣田濕天然氣CO2腐蝕環境,進行了不同氣體溫度、濕氣-管壁溫差的濕氣冷凝腐蝕實驗,研究了溫度對X70鋼腐蝕形態、速率的變化規律.利用掃描電鏡和能譜儀,分析了腐蝕產物膜的微觀形貌和成分,并與高溫高壓釜中全水相實驗結果進行了對比.建立了濕氣管道腐蝕預測模型,初步探討了濕氣溫度、管壁溫度、溫差、液膜溫度和冷凝率等重要濕氣參數對濕氣頂部腐蝕的影響.結果表明:在相同管壁溫度(5℃)下,濕氣溫度升高使X70管線鋼腐蝕速率升高;在相同的濕氣溫度(25℃和45℃)下,X70鋼的腐蝕速率隨管壁溫度的升高而略有下降;在20~45℃范圍內,腐蝕產物膜與基體的結合較弱,極易從基體剝落,腐蝕形態均為全面腐蝕.

     

    Abstract: With a high-temperature and high-pressure condensation autoclave simulating the circumstance of CO2 corrosion in wet gas pipelines,the variation in corrosion behavior and morphology of X70 pipeline steel was studied by changing the wet gas temperature and the temperature difference between the wet gas and the pipe wall.Scanning electron microscopy(SEM) and energy dispersive spectrometry(EDS) were employed to analyze the morphologies and characteristics of corrosion scales on the steel.The results were compared with those under solution-immersed conditions in a high-temperature and high-pressure autoclave.Using a corrosion prediction model,the influence of some important parameters on corrosion at the top of wet gas pipelines were preliminary studied,such as wet gas and pipe wall temperatures,temperature difference,condensed liquid film temperature and condensation rate.The results show that at the same temperature of the pipe wall(5℃),the corrosion rate increases with the wet gas temperature rising;while at the same temperature of wet gas(25℃ and 45℃),the corrosion rate decreases slightly with the pipe wall temperature rising.In the temperature range of 20 to 45℃,corrosion scales are easily peeled off from the substrate,and uniform corrosion is the predominant morphology.

     

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