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電化學方法研究混凝土模擬液中細晶粒鋼的耐蝕性

Corrosion resistance of fine-grained rebar in simulated concrete pore solutions by means of electrochemical methods

  • 摘要: 通過腐蝕電位、線性極化法與循環極化法等電化學方法研究了細晶粒鋼和普通低碳鋼在模擬混凝土孔溶液中的均勻腐蝕與點蝕行為,并考慮了砂磨和未處理兩種鋼筋表面狀況對鋼筋腐蝕行為的影響.結果表明,細晶粒鋼與普通低碳鋼在模擬液中的耐均勻腐蝕的能力很接近;砂磨鋼筋的鈍化效果比未處理鋼筋好;腐蝕末期砂磨鋼筋表現出比未處理鋼筋更強的抑制均勻腐蝕能力.循環極化測試表明:砂磨鋼筋由于其相對均勻的表面組織形貌,故表現出比未處理鋼筋更好的抑制點蝕能力;其次,由于細晶粒鋼含有較多晶界,晶界處含有較多易發生點蝕的夾雜,故表面未處理細晶粒鋼發生點蝕的概率稍大于未處理低碳鋼.

     

    Abstract: Uniform and pitting corrosion behaviors of fine-grained rebar and low-carbon rebar in simulated concrete pore(SCP) solutions were investigated by means of corrosion potential,linear polarization resistance(LPR) and cyclic polarization.The influence of two different rebar surface conditions,i.e.,sandblasted and as-received,on the corrosion behavior of the rebar was taken into consideration.The results indicate that fine-grained rebar and low-carbon rebar show almost the same uniform corrosion behavior,and the passivation effects are better for sandblasted rebar than as-received rebar.In the latter period of corrosion,sandblasted rebar shows a higher uniform corrosion resistance than as-received rebar.Cyclic polarization measurements reveal that sandblasted rebar performs better in delaying pitting corrosion due to the relatively homogeneous surface than as-received rebar.Since more impurity-containing grain boundaries in fine-grained rebar facilitate the occurrence of pitting corrosion,the probability of pitting corrosion for as-received fine-grained rebar is slightly higher than that of as-received low-carbon rebar.

     

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